rgb color picking

is it possible to use the colorpicker with rgb lighting?   Though I am currently forced to use, against my will, a series of RGB scoops in order to light my cyc.  I probably will be getting some sky-cyc lights from altman that have RGBA in them in order to mix lighting on my Cyc.  My question is, can you use the color picker to attempt this?  I have already attempted patch these lights in as generic RGB and have gotten them to be able to be manipulated with the wheels as opposed to my usual method of throwing them on to a masterplayback and mixing that way.  However, the colorpicker did not seem to want to work in that capacity.  Is colorpicker only for cmy devices or led lights?  This is all for educational purposes stricktly, as I have heard that what I am attempting will not be nearly as effective as just mixing them by hand without the colorpicker...but I wanted to attempt it anywho.

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